Electron correlation and Hund's rule
نویسندگان
چکیده
منابع مشابه
Electron Correlation and Hund ’ s Rule
s It is suggested that simple electronic shielding effects induced by wave function antisymmetrization tend to govern the energy ordering of singlet and triplet terms within a two-electron atomic configuration. This approach gives rise to the following alternating rule: For the term of greatest orbital angular momentum within a configuration, the triplet lies below the singlet. The energy order...
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ژورنال
عنوان ژورنال: International Journal of Quantum Chemistry
سال: 1980
ISSN: 0020-7608,1097-461X
DOI: 10.1002/qua.560180403